Also the food comes up pretty high on the list of incentives for working at Google. Who knows how many talented people now work at Google because of their chefs.
Also consider opportunity cost. The chef could have opened a restaurant instead and perhaps also earn a lot of money that way.
According to BusinessWeek, new restaurants are not quite as risky as people perceive. Only 60% of new restaurants fail or are sold in three years[1], which is a bit higher but similar rate to any new business.[2]
I can't find any good numbers on tech startups with some Googling other than the oft-quoted 90%. This is hard to compare, because you might earn some sort of salary while the startup is in operation, but it closes down because it fails to meet growth targets.
But on balance it seems to me the startup is still riskier.
Also consider opportunity cost. The chef could have opened a restaurant instead and perhaps also earn a lot of money that way.