There are different degrees of popularity. The amount of people that shared files using FTP and usenet pales in comparison to the amount of users of P2P networks. I think it's fair to say that Napster and then P2P made MP3 ubiquitous.
I think Winamp, which predated Napster by a couple of years, was really the turning point that made MP3 popular. Really MP3 made P2P networks popular, rather than the other way around.