It's not the material that's the problem in many places, but the cost. There are reports of people using post-exposure prophylaxis drugs over condoms because they're cheaper!
Only in places that allow use of cheap generic post-exposure drugs produced in India. Unfortunately the very same drugs in Europe are hell expensive. They should be probably subsidized by the country like Germany which is famous for its sex industry.
More info: http://www.bbc.co.uk/news/magazine-24942903